4-Chloro-N-(3,4-dimethylphenyl)benzamide
نویسندگان
چکیده
In the title compound, C(15)H(14)ClNO, the N-H bond is trans to the C=O bond. The dihedral angle between the two aromatic rings is 5.5 (2)°. In the crystal, inter-molecular N-H⋯O hydrogen bonds link the mol-ecules into chains running along the a axis.
منابع مشابه
N-(3,4-Dimethylphenyl)benzamide
The conformation of the NH bond in the structure of the title compound (N34DMPBA), C(15)H(15)NO, is anti to the meta-methyl substituent in the aniline ring, similar to that observed with respect to the meta-chloro substituent in N-(3,4-dichloro-phen-yl)benzamide (N34DCPBA), but in contrast to the syn conformation observed with respect to the meta-methyl substituent in N-(3,4-dimethyl-phen-yl)ac...
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The conformations of the N-H and C=O bonds in the structure of the title compound (N26DMP4CBA), C(15)H(14)ClNO, are anti to each other, similar to that observed in N-phenyl-benzamide, N-(3,4-dimethyl-phen-yl)benzamide, N-(2,6-dichloro-phen-yl)benzamide and other benzanilides. There are three mol-ecules in the asymmetric unit of N26DMP4CBA. The central amide group is tilted with respect to the b...
متن کامل2-Chloro-N-(3,4-dimethylphenyl)benzamide
In the title compound, C(15)H(14)ClNO, the conformation of the N-H bond is anti to the meta-methyl group in the aniline ring, while that of the C=O bond is anti to the ortho-chloro group in the benzoyl ring. The mean planes through the two benzene rings make a dihedral angle of 80.8 (2)°. In the crystal, mol-ecules are linked by inter-molecular N-H⋯O hydrogen bonds, forming column-like chains a...
متن کاملN-(4-Methylphenyl)benzamide
The structure of the title compound, C(14)H(13)NO, resembles those of N-(2-chloro-phen-yl)benzamide, 2-chloro-N-phenyl-benzamide, N-(2,3-dichloro-phen-yl)benzamide, N-(3,4-dichloro-phen-yl)benzamide and 2-chloro-N-(2-chloro-phen-yl)benzamide with similar bond parameters. The benzene and methylphenyl rings have a dihedral angle of 63.41 (5)°, while the amide group makes a dihedral angle of 20.5 ...
متن کامل4-Chloro-N-(3,5-dimethylphenyl)benzamide
In the mol-ecular structure of the title compound, C(15)H(14)ClNO, the amide group forms dihedral angles of 15.8 (2) and 27.2 (2)°, respectively, with the benzoyl and aniline rings, while the angle between the benzoyl and aniline rings is 11.5 (1)°. The crystal structure is stabilized by N-H⋯O hydrogen bonds, which give rise to infinite chains running along the c axis.
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